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Ramos, who left the UEFA Cup champions on Friday clearing his way for a move to north London, has signed a four-year deal with Spurs, the club announced.
His first game in charge will be against Blackpool in the Carling Cup on Wednesday, with development coach Clive Allen and youth team boss Alex Inglethorpe in charge for SUnday's Premier League clash against Blackburn.
"I greatly appreciate the opportunity to work as head coach at Tottenham Hotspur, a club with a great tradition and history," Ramos said.
"Ever since I started my coaching career I have wanted to work in England. It is my sincere hope that I can repay the faith the Spurs Board has shown in me." More detail......